![Foto de Miguel Ángel](/img/nophoto.png)
Miguel Ángel
Sierra Rodríguez
Publications by the researcher in collaboration with Miguel Ángel Sierra Rodríguez (20)
2021
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Role of imine isomerization in the stereocontrol of the Staudinger reaction between ketenes and imines
RSC Advances, Vol. 12, Núm. 1, pp. 104-117
2013
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Computational Chemistry; A useful tool for the chemical synthesis of complex molecules, heterocycles and catalysts
Synlett, Vol. 24, Núm. 5, pp. 535-549
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More Dead Ends and Detours: En Route to Successful Total Synthesis
Wiley-VCH
2011
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Photochemistry of group 6 fischer carbene complexes: Beyond the photocarbonylation reaction
Accounts of Chemical Research, Vol. 44, Núm. 7, pp. 479-490
2009
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Dyotropic reactions: Mechanisms and synthetic applications
Chemical Reviews, Vol. 109, Núm. 12, pp. 6687-6711
2008
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Computational and experimental tools in solving some mechanistic problems in the chemistry of Fischer carbene complexes
Chemical Communications, pp. 4671-4682
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DFT study on the Diels-Alder cycloaddition between alkenyl-M(0) (M = Cr, W) carbene complexes and neutral 1,3-dienes
Journal of Organic Chemistry, Vol. 73, Núm. 6, pp. 2083-2089
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Deeper insight into the mechanism of the reaction of photogenerated metallaketenes and imines
Journal of the American Chemical Society, Vol. 130, Núm. 42, pp. 13892-13899
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The mechanism of the ketene-imine (Staudinger) reaction in its centennial: Still an unsolved problem?
Accounts of Chemical Research, Vol. 41, Núm. 8, pp. 925-936
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The noncarbonylative photochemistry of group 6 fischer carbene complexes
European Journal of Inorganic Chemistry, pp. 2454-2462
2007
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Double group transfer reactions as indicators of aromatic stabilization
European Journal of Organic Chemistry, pp. 5410-5415
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In-plane aromaticity in double group transfer reactions
Journal of Organic Chemistry, Vol. 72, Núm. 4, pp. 1488-1491
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Mechanism of the generation of ketenimine-M(CO)n complexes (M = Cr, W, Fe) from fischer carbenes and isocyanides
Organometallics, Vol. 26, Núm. 12, pp. 3010-3017
2006
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Effect of the metal fragment in the thermal cycloaddition between alkynyl metal(0) Fischer carbene complexes and nitrones
Journal of Organic Chemistry, Vol. 71, Núm. 16, pp. 6178-6184
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Stereoelectronic effects on type I 1,2-dyotropic rearrangements in vicinal dibromides
Chemistry - A European Journal, Vol. 12, Núm. 24, pp. 6323-6330
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The photochemical reactivity of the "photo-inert" tungsten (Fischer) carbene complexes
Angewandte Chemie - International Edition, Vol. 45, Núm. 1, pp. 125-128
2005
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Computational and experimental studies on the mechanism of the photochemical carbonylation of Group 6 Fischer carbene complexes
Chemistry - A European Journal, Vol. 11, Núm. 20, pp. 5988-5996
2004
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Structure and conformations of heteroatom-substituted free carbenes and their group 6 transition metal analogues
Organometallics, Vol. 23, Núm. 5, pp. 1065-1071
2003
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Light-induced aminocarbene to imine dyotropic rearrangement in a chromium(0) center: An unprecedented reaction pathway
Journal of the American Chemical Society, Vol. 125, Núm. 32, pp. 9572-9573
2000
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A theoretical - Experimental approach to the mechanism of the photocarbonylation of chromium(0) (Fischer) - Carbene complexes and their reaction with imines [2]
Journal of the American Chemical Society